Robust Triboelectric Nanogenerator Achieved by Centrifugal Force Induced Automatic Working Mode Transition

Abstract Material abrasion in contact‐based freestanding mode‐triboelectric nanogenerators (FS‐TENGs) seriously deteriorates device mechanical durability and electrical stability, which causes TENGs to be only applicable in the harvesting of mechanical energy at low‐frequency. Here, a wide‐frequency and ultra‐robust rotational TENG is reported that is composed of a built‐in traction rope structure and capable of transforming from contact mode to non‐contact mode automatically as driven by the centrifugal force. With optimizing the fixed x and y position on slider and center shaft, respectively, the mode transition threshold speed can be reduced to 225 rpm. Additionally, the automatic working mode transition TENG exhibits excellent electrical stability, which can maintain 90% electric output after over 24 h of continuous operation, while the contact and non‐contact mode TENGs only retain 30% and 2% output, respectively. The high stability and large output density ensure its usage in the fast and effective charging of commercial capacitors or electronics. This work provides a prospective strategy for rotational TENGs to extend the frequency operation region and mechanical durability for practical applications.