Robust magnetic anisotropy of a monolayer of hexacoordinate Fe(<scp>ii</scp>) complexes assembled on Cu(111)

Massine Kelaï; Benjamin Cahier; Mihail Atanasov; Frank Neese; Yongfeng Tong; Luqiong Zhang; Amandine Bellec; Olga Iasco; Éric Rivière; Régis Guillot; Cyril Chacon; Yann Girard; Jérôme Lagoute; Sylvie Rousset; Vincent Repain; Edwige Otero; Marie‐Anne Arrio; Philippe Sainctavit; Anne‐Laure Barra; Marie‐Laure Boillot; Talal Mallah

doi:10.1039/d1qi00085c

Robust magnetic anisotropy of a monolayer of hexacoordinate Fe(<scp>ii</scp>) complexes assembled on Cu(111)

Inorganic Chemistry Frontiers 8(9): 2395-2404

Article 2021 English

Abstract

1 min read

The tris pyrazolyl borate ligand imposes a rigid scaffold around Fe( ii ) ensuring a robust magnetic anisotropy when the molecules assembled as monolayers suffer from the dissymmetric environment of the substrate/vacuum interface.

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Robust magnetic anisotropy of a monolayer of hexacoordinate Fe(<scp>ii</scp>) complexes assembled on Cu(111)

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