Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes

Christopher J Chang; Donald W. Low; Harry B. Gray

doi:10.1021/ic961023a

Abstract

1 min read

Nitrogen atom transfer from salen-derived nitridomanganese(V) to manganese(III) Schiff-base complexes occurs under aerobic conditions in solution at room temperature. A mechanism involving chloride dissociation followed by the formation and decay of a binuclear μ-nitrido-activated complex accounts satisfactorily for the observed kinetics data.

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Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes

Abstract

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