Regiospecific Side‐Chain Functionalization of Linear Low‐Density Polyethylene with Polar Groups

Chulsung Bae; John F Hartwig; Hoyong Chung; Nicole K. Harris; K.A. Switek; Marc A. Hillmyer

doi:10.1002/ange.200501837

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Regiospecific Side‐Chain Functionalization of Linear Low‐Density Polyethylene with Polar Groups

Article 2005 en

Abstract

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Funktionelle Gruppen am Ende: Unter Rh-Katalyse ist käufliches lineares Niederdruckpolyethylen (LLDPE) mit Borreagentien selektiv funktionalisierbar. Die anschließende Oxidation sowie weitere Umwandlungen der borhaltigen Polymere führen eine Vielfalt polarer Funktionen (z. B. Hydroxy-, Amino- oder Formylgruppen) an den Enden und Seitenketten ein (siehe Schema).

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