Redox potential tuning by redox-inactive cations in nature's water oxidizing catalyst and synthetic analogues

Vera Krewald; Frank Neese; Dimitrios A. Pantazis

doi:10.1039/c5cp07213a

Redox potential tuning by redox-inactive cations in nature's water oxidizing catalyst and synthetic analogues

Physical Chemistry Chemical Physics 18(16): 10739-10750

Article 2016 English

Abstract

1 min read

Fundamental differences between synthetic manganese clusters and the biological water oxidizing catalyst are demonstrated in the modulation of their redox potential by redox-inactive cations.

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