Rational Medium‐Range Charge Transfer Strategy Toward Highly Efficient Violet‐Blue Organic Light‐Emitting Diodes with Narrowed Emission

The spectral narrowing engineering of pure-organic emitters attracts great research interests in realizing high color purity. Here, the adjusted medium-range charge transfer (MCT) strategy of TIC-BO with rigid planar structure by fusing two typical UV-emitting multiple resonance (MR) fragments via the ingenious double-halide cyclized coupling reaction is reported. The resulting TIC-BO with MCT nature shows efficient violet-blue emission in dilute toluene and evaporated host-guest films, and desirably narrowed spectra are achieved by the suppression of structural relaxation and the shortened charge transfer states. The single-doped device with TIC-BO as emitter shows narrowed violet-blue electroluminescence peaked at 428 nm with full-width at half-maximum of 43 nm (0.28 eV), and the Commission Internationale de l'Éclairage coordinates of (0.160, 0.050). A maximum external quantum efficiency (EQE_max ) of 20.50% is achieved, which is among the best results of the corresponding violet-blue emitting region. Further introduction of a stronger electron-donating carbazole group makes TIC-BNO exhibit red-shifted sky-blue emission with MR-dominant properties, and good device performance is received with EQE_max of 34.58%. The outstanding performances of TIC-BO successfully demonstrate the significance and prospect of the proposed molecular design strategy.