Quantitative Kinetics of HO₂ Reactions with Aldehydes in the Atmosphere: High-Order Dynamic Correlation, Anharmonicity, and Falloff Effects Are All Important

Kinetics provides the fundamental parameters for elucidating sources and sinks of key atmospheric species and for atmospheric modeling more generally. Obtaining quantitative kinetics in the laboratory for the full range of atmospheric temperatures and pressures is quite difficult. Here, we use computational chemistry to obtain quantitative rate constants for the reactions of HO₂ with HCHO, CH₃CHO, and CF₃CHO. First, we calculate the high-pressure-limit rate constants by using a dual-level strategy that combines conventional transition state theory using a high level of electronic structure wave function theory with canonical variational transition state theory including small-curvature tunneling using density functional theory. The wave-function level is beyond-CCSD(T) for HCHO and CCSD(T)-F12a (Level-A) for XCHO (X = CH₃, CF₃), and the density functional (Level-B) is specifically validated for these reactions. Then, we calculate the pressure-dependent rate constants by using system-specific quantum RRK theory (SS-QRRK) and also by an energy-grained master equation. The two treatments of the pressure dependence agree well. We find that the Level-A//Level-B method gives good agreement with CCSDTQ(P)/CBS. We also find that anharmonicity is an important factor that increases the rate constants of all three reactions. We find that the HO₂ + HCHO reaction has a significant dependence on pressure, but the HO₂ + CF₃CHO reaction is almost independent of pressure. Our findings show that the HO₂ + HCHO reaction makes important contribution to the sink for HCHO, and the HO₂ + CF₃CHO reaction is the dominant sink for CF₃CHO in the atmosphere.