Poly(dimethylsiloxane)‐Substituted 2,2′:6,2″‐Terpyridines: Synthesis and Characterization of New Amphiphilic Supramolecular Diblock Copolymers — Steve Landsmann (2008) | RDL Network
Poly(dimethylsiloxane)‐Substituted 2,2′:6,2″‐Terpyridines: Synthesis and Characterization of New Amphiphilic Supramolecular Diblock Copolymers
Article 2008 en
Authors
SL
Steve Landsmann
AW
Andreas Winter
MC
Manuela Chiper
Abstract
1 min read
Abstract Terpyridine‐modified hydrophobic poly(dimethylsiloxane) and hydrophilic poly(ethylene oxide) were combined to new metallo‐supramolecular AB‐diblock copolymers by utilizing Ru(II) ions. The polymers were synthesized by hydrosilylation of heteroleptic allyloxy‐functionalized Ru(II) complexes. The amphiphilic AB‐diblock copolymers were used to prepare micelles in an aqueous environment, which were subsequently characterized by dynamic light scattering and cryogenic transmission electron microscopy. magnified image
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