Photoluminescent Thin Films of Room-Temperature Glassy Tris(keto-hydrozone) Discotic Liquid Crystals and Their Nanocomposites with Single-Walled Carbon Nanotubes for Optoelectronics

This study addresses the photoresponse of liquid-crystalline tris(keto-hydrozone) discotic (TKHD)─a star-shaped molecular structure with three branches. Object of our research interest was also TKHD filled with single-walled carbon nanotubes (SWCNTs) at a concentration of 1 wt %. At room temperature, the discotic liquid crystals in thin films (thickness 3 μm) of both TKHD and nanocomposite SWCNT/TKHD were in a glassy state. Such glassy thin films exhibited photoluminescence ranging from the deep-red to the near-infrared spectral region, being attractive for organic optoelectronics. The addition of SWCNTs to TKHD was found to stabilize the photoluminescence of TKHD, which is of significance for optoelectronic device applications. The photothermoelectrical response of highly conductive SWCNT/TKHD nanocomposite films was characterized by electrical impedance spectroscopy in the frequency range from 1 Hz to 1 MHz of the applied electric field. It was elucidated that the reversible photothermoelectrical effect in SWCNT/TKHD films occurs through SWCNTs and their network.