Photochemical Formation of a Stable Oxalic Acid Orthoamide with a Propellane Structure

Erich Tauer; Karl‐Heinz Grellmann; Mathias Noltemeyer; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1002/anie.198903381

Photochemical Formation of a Stable Oxalic Acid Orthoamide with a Propellane Structure

Angewandte Chemie International Edition 28(3): 338-339

Article 1989 English

Abstract

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The first stable orthoamide of oxalic acid with the substitution pattern of a hexaaminoethane, the “4.4.4” propellane 2, was obtained by irradiation of 1 in cyclohexane (R = CH3).

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Photochemical Formation of a Stable Oxalic Acid Orthoamide with a Propellane Structure

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