Passive-cooling building materials can achieve cooling without external energy consumption, which is an energy-saving and environmentally friendly cooling method. However, the existing passive-cooling building materials have the limitations of high cost, complicated processes, and a toxic organic solvent, which hinders the passive-cooling technology applied in practical building. To overcome these limitations, we developed a facile, high-efficiency, non-toxic, and superhydrophobic passive-cooling building coating (SPCBC) with an efficient cooling capability and excellent durability that was composed of polydimethylsiloxane and SiO2. The fabricated SPCBC demonstrated a high reflectance and a high emittance, showing a superior cooling capability with a 14 °C temperature drop compared with a bare cement surface on a hot summer day. In addition, the SPCBC could not be wetted or contaminated by muddy water, corrosive aqueous solutions, or dust, which presented an excellent anti-fouling and self-cleaning capability. Moreover, the fabricated SPCBC could work outdoors for 30 days, withstand UV irradiation for 30 days, and resist accelerated aging for 100 h without any significant changes in the superhydrophobicity and the cooling capability, meaning that the SPCBC had an outstanding durability. This work provides a new method to facilitate passive-cooling technology to apply in practical building in hot weather regions of the world.
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