Octanuclear Bis(triple-helical) Metal(II) Complexes

Rolf W. Saalfrank; Norbert Löw; Stefan Trümmer; In Memory: G.M. Sheldrick (1942–2025); M. Teichert; Dietmar Stalke

doi:10.1002/(sici)1099-0682(199805)1998:5<559::aid-ejic559>3.0.co;2-m

Octanuclear Bis(triple-helical) Metal(II) Complexes

European Journal of Inorganic Chemistry 1998(5): 559-563

Article 1998 English

Abstract

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The reaction of H2L1 and H2L2 with divalent metal ions leads to octanuclear bis(triple-helical) metal(II) complexes of the general composition [Zn8O2L26] (3) and [M8O2L16] (4: M = Cd2+; 5: M = Mn2+). NMR studies of the diamagnetic cadmium complex 4c show six equivalent ligands. Unambiguous characterisation of 5b was achieved by X-ray crystallographic analysis.

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