NiFe Layered-Double-Hydroxide Nanosheet Arrays on Graphite Felt: A 3D Electrocatalyst for Highly Efficient Water Oxidation in Alkaline Media

It is of great importance to rationally design and develop earth-abundant nanocatalysts for high-efficiency water electrolysis. Herein, NiFe layered double hydroxide was in situ grown hydrothermally on a 3D graphite felt (NiFe LDH/GF) as a high-efficiency catalyst in facilitating the oxygen evolution reaction (OER). In 1.0 M KOH, NiFe LDH/GF requires a low overpotential of 214 mV to deliver a geometric current density of 50 mA cm^-2 (η_{50 mA cm^-2} = 214 mV), surpassing that NiFe LDH supported on a 2D graphite paper (NiFe LDH/GP; η_{50 mA cm^-2} = 301 mV). More importantly, NiFe LDH/GF shows good durability at 50 mA cm^-2 within 50 h of OER catalysis testing and delivers a faradaic efficiency of nearly 100% in the electrocatalysis of OER.