Neuartige Koordination eines cyclopentadienylrings im heterotrimetallischen organoyttrium-komplex Li[Cp2Y(FcN)2] (FcN = 2-dimethylaminomethylferrocenyl)

K. Jacob; Martina Schäfer; Alexander Steiner; In Memory: G.M. Sheldrick (1942–2025); Frank T. Edelmann

doi:10.1016/0022-328x(94)05088-s

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In Memory: G.M. Sheldrick (1942–2025)

Neuartige Koordination eines cyclopentadienylrings im heterotrimetallischen organoyttrium-komplex Li[Cp2Y(FcN)2] (FcN = 2-dimethylaminomethylferrocenyl)

Journal of Organometallic Chemistry 487(1-2): C18-C20

Article 1995 English

Authors

KJ
K. Jacob
MS
Martina Schäfer
AS
Alexander Steiner

Abstract

1 min read

Treatment of bis(cyclopentadienyl)yttrium(III) chloride with two equivalents of 2-dimethylaminomethylferrocenyl lithium affords the novel heterotrimetallic complex Li[Cp2Y(FcN)2] (1). A single-crystal X-ray structure determination of 1 reveals the presence of an unprecedented bonding mode of a cyclopentadienyl ring.

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Neuartige Koordination eines cyclopentadienylrings im heterotrimetallischen organoyttrium-komplex Li[Cp2Y(FcN)2] (FcN = 2-dimethylaminomethylferrocenyl)

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