Negative Solvatochromism of Ferrocenyl Methine Dyes

Abdullah Mohamed Asiri; Muhammed S. Al-Amoudi

doi:10.4197/sci.21-1.13

Abstract

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Abstract. A novel solvatochromic ferrocenyl methine dyes has been synthesized by condensation of ferrocen-3-caboxaldehyde with active methylene compounds under Knoevengel conditions and characterized by UV-vis in a range of solvents. Compound 1a has a red shift in π-π* and a blue shift increases with solvent polarity in the MLCT (M→A) while 1b-1d variation of red as well as blue shifts from both states. No d-d transition is observed in these compounds. These shifts are interpreted by different dipole moments in the ground and excited state as well as solvent interaction between solute/solvent and H-bonding with the acceptor.

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Negative Solvatochromism of Ferrocenyl Methine Dyes

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