Multinuclear silver(<scp>i</scp>) XPhos complexes with cyclooctatetraene: photochemical C–C bond cleavage of acetonitrile and cyanide bridged Ag cluster formation — Abdessamad Grirrane (2016) | RDL Network
Multinuclear silver(<scp>i</scp>) XPhos complexes with cyclooctatetraene: photochemical C–C bond cleavage of acetonitrile and cyanide bridged Ag cluster formation
Dalton Transactions 45(13): 5444-5450
Article 2016 English
Authors
AG
Abdessamad Grirrane
EÁ
Eleuterio Álvarez
JA
Josep Albero
Abstract
1 min read
Fluxional cationic multi-silver(<sc>i</sc>) complexes [(XPhos-Ag)<sub>n</sub>(COT)][SbF<sub>6</sub>]<sup>n</sup> and Ag clusters [(XPhos-Ag)<sub>2</sub>(μ-CN)<sub>n</sub>(μ-Ag)<sub>n−1</sub>] (<italic>n</italic> = 1, 2, 3, 4) have been isolated and fully characterized.
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