Metal–organic frameworks with designed chiral recognition sites

Cory Valente; Eunwoo Choi; Matthew E. Belowich; Christian J. Doonan; Qiaowei Li; Travis B. Gasa; Youssry Y. Botros; Omar M Yaghi; J. Fraser Stoddart

doi:10.1039/c0cc00997k

Abstract

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Linking struts containing Cram-like bisbinaphthyl[22]crown-6 with Zn(4)O(CO(2))(6) joints affords metal-organic frameworks with chiral recognition sites that are highly designed, ordered and placed in a precise manner throughout the entire crystal.

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