Some examples of ordering in thin inorganic nanocrystalline films, structure of dye-sensitized thin films on optically transparent nanocrystalline electrodes, inorganic epitaxial growth and first heterosupermolecules with nanoparticles as coordination center are accumulated in this short review of our results and literary data to discuss the questions of morphology and optoelectronic properties of nanocrystalline junctions in resulted assembled structures.
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