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Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis — Nora S. Radu (1994) | RDL Network
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Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis
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T Don Tilley
University of California, Berkeley
Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis
Article
1994
en
Authors
NR
Nora S. Radu
PG
P. Gantzel
T Don Tilley
University of California, Berkeley
Abstract
1 min read
Reactions of [{Ln(C5Me5)2H}2](Ln = Y, Sm) with [W(C5H5)2H2] afford the σ-bond metathesis products [(C5Me5)2Ln(µ-η1, η5-C5H4)(µ-H)2W(C5H5)], via dehydrocoupling between the Ln–H bond and the C–H (but not the weaker W–H) bond of [W(C5H5)2H2].
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