The oscillator strengths of the vibrationally allowed n → π* transitions of acetaldehyde and acetone and their deuterated derivatives are shown to depend mainly on the vibrational frequencies of the mixing modes in the deuterated and undeuterated species. Quantitative agreement is found between the calculated and observed intensity ratios fD/fH.
H. B. Singh, Louis J. Salas, R. B. Chatfield, E. Czech, Alan Fried, J. Walega, M. J. Evans, Brendan D. Field, Daniel J. Jacob, Donald R Blake, Brian G. Heikes, R. W. Talbot, G. W. Sachse, J. H. Crawford, M. A. Avery, S. T. Sandholm, Henry E. Fuelberg
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