Iridium‐Catalyzed Regio‐ and Enantioselective N‐Allylation of Indoles

Iridium verschmäht C: Hoch regio- und enantioselektive iridiumkatalysierte N-Allylierungen von Indolen ergänzen üblichere Umsetzungen, in denen die Indole als Kohlenstoffnucleophile wirken (siehe Schema). Die Reaktionen führen zu stark enantiomerenangereicherten N-Allylindolen, aus denen sich leicht enantiomerenangereicherte 3-(1H-Indol-1-yl)-N-methyl-3-arylpropan-1-amine, Dihydropyrrolo[1,2-a]indole und (Indol-1-yl)propansäurederivate erhalten lassen. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.