Intrinsic Optical Properties of Vanadium Dioxide near the Insulator−Metal Transition

We studied the insulator-metal transition (IMT) in single-domain, single crystalline vanadium dioxide (VO(2)) microbeams with infrared microspectroscopy. The unique nature of such samples allowed us to probe the intrinsic behavior of both insulating and metallic phases in the close vicinity of IMT, and investigate the IMT driven by either strain or temperature independently. We found that the VO(2) insulating band gap narrows rapidly upon heating, and the infrared response undergoes an abrupt transition at both strain- and temperature-induced IMT. The results are consistent with recent studies attributing the opening of VO(2) insulating band gap to a correlation-assisted Peierls transition.