Insertion of Platinum into the Sulfur‐Nitrogen Bond of a 1,2,4‐Thiadiazole: Synthesis of a Six‐membered Metallaheterocycle — Herbert W. Roesky (1984) | RDL Network
Insertion of Platinum into the Sulfur‐Nitrogen Bond of a 1,2,4‐Thiadiazole: Synthesis of a Six‐membered Metallaheterocycle
Angewandte Chemie International Edition 23(12): 971-972
Article 1984 English
Authors
HR
Herbert W. Roesky
HH
Hartmut Hofmann
PJ
Peter G. Jones
Abstract
1 min read
The chelate complex 3 containing a novel C2N2SPt heterocycle is formed by insertion of Pt at the SN bond of the dinitrile 1 on reaction with the complex 2. Complexes such as 3 deserve attention, since coordination compounds of platinum find application in homogeneous catalysis and cancer therapy.
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