<i>ortho</i>‐Palladated Dibenzyl Sulfides and Sulfoxides from Palladium Carboxylates
Angewandte Chemie International Edition 20(4): 382-383
Article 1981 English
Authors
RR
Reinhold Rüger
WR
Walter Rittner
PJ
Peter G. Jones
Abstract
1 min read
Suitable reagents for ortho-palladation are palladium(II) acetate and trifluoroacetate. Thus, it is possible to prepare the complexes (1) from these compounds and dibenzyl sulf-oxide or dibenzyl sulfide. Hitherto, only arylthioketones could be ortho-palladated (R = CH3, CF3; X = SO1 S).
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