Gold (I) and (III) catalyze Suzuki cross-coupling and homocoupling, respectively

Camino González‐Arellano; Avelino Avelino; M. Iglesias; Félix Sánchez

doi:10.1016/j.jcat.2005.12.015

Gold (I) and (III) catalyze Suzuki cross-coupling and homocoupling, respectively

Journal of Catalysis 238(2): 497-501

Article 2006 English

Abstract

1 min read

Trinuclear triphenylphosphine 1,2Au(I) complexes with the [N,N,O]-tridentate unsymmetrical Schiff bases (1,2) catalyze the Suzuki cross-coupling reaction to afford nonsymmetrical biaryls in good yields, whereas the 1,2Au(III) complexes give only arylboronic homocoupling.

Discussion(0)

No comments yet. Be the first to comment.

Related publications

Article2007

Heterogenized Gold(I), Gold(III), and Palladium(II) Complexes for C-C Bond Reactions

Avelino Avelino, Camino González‐Arellano, M. Iglesias, Susana Pérez-Ferreras, Félix Sánchez

Article2008

Soluble Gold and Palladium Complexes Heterogenized on MCM‐41 Are Effective and Versatile Catalysts

Camino González‐Arellano, Avelino Avelino, M. Iglesias, Félix Sánchez

Article2006

New Heterogenized Gold(<scp>I</scp>)‐Heterocyclic Carbene Complexes as Reusable Catalysts in Hydrogenation and Cross‐Coupling Reactions

Avelino Avelino, Enrique Gutiérrez‐Puebla, M. Iglesias, Ángeles Monge, Susana Pérez-Ferreras, Félix Sánchez

Advanced Synthesis & Catalysis

Article2005

Stabilization of Au(III) on heterogeneous catalysts and their catalytic similarities with homogeneous Au(III) metal organic complexes

Silvio Carrettin, Avelino Avelino, M. Iglesias, Félix Sánchez

Applied Catalysis A General

Article2020

Palladium (II) Complexes Containing 2-Phenylpyridine Derivatives: Synthesis, Molecular Structures, and Catalytic Activity for Suzuki–Miyaura Cross-Coupling Reactions

A. Adamson, Yudha P. Budiman, Ibraheem A. I. Mkhalid, R. Muhammad, Muhammad Nadeem Arshad, Maha Alhaddad, Abdullah Mohamed Asiri