Gold‐Catalyzed Intramolecular Aminoarylation of Alkenes: CC Bond Formation through Bimolecular Reductive Elimination

Zweikernige Goldbromidkomplexe katalysieren die Aminoarylierung nichtaktivierter terminaler Olefine mit Arylboronsäuren und dem Oxidationsmittel Selectfluor bei Raumtemperatur. Ein Gold(I)-Gold(III)-Katalysezyklus mit einer bimolekularen reduktiven Eliminierung als Schlüsselschritt der C-C-Verknüpfung wird vorgeschlagen. dppm=Bis(diphenylphosphanyl)methan. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.