From Triboelectric Nanogenerator to Multifunctional Triboelectric Sensors: A Chemical Perspective toward the Interface Optimization and Device Integration

Abstract Triboelectric nanogenerators (TENGs) have intrigued scientists for their potential to alleviate the energy shortage crisis and facilitate self‐powered sensors. Triboelectric interfaces containing triboelectric functionalized molecular groups and tunable surface charge densities are important for improving the electrical output capability of TENGs and the versatility of future electronics. In this review, following an introduction to the fundamental progress of TENG systems for mechanic energy harvesting, surface modifications that aim to increase the surface charge density and functionality are highlighted, with an emphasis on interfacial chemical modification and triboelectric energetics/dynamics optimization for efficient electrostatic induction and charge transfer. Recent advances in assemblies of multifunctional triboelectric sensing are briefly introduced, and future challenges and chemical perspectives in the field of TENG‐based electronics are concisely reviewed. This review presents and advances the understanding of the state‐of‐the‐art chemical strategies toward rational triboelectric interface engineering and system assembly and is expected to guide the rational design of highly efficient and versatile triboelectric sensing.