Flexible All‐Inorganic Perovskite Photodetector with a Combined Soft‐Hard Layer Produced by Ligand Cross‐Linking

Although perovskite nanocrystals have attracted considerable interests as emerging semiconductors in optoelectronic devices, design and fabrication of a deformable structure with high stability and flexibility while meeting the charge transport requirements remain a huge challenge. Herein, a combined soft-hard strategy is demonstrated to fabricate intrinsically flexible all-inorganic perovskite layers for photodetection via ligand cross-linking. Perfluorodecyltrichlorosilane (FDTS) is employed as the capping ligand and passivating agent bound to the CsPbBr₃ surface via Pb-F and Br-F interactions. The SiCl head groups of FDTS are hydrolyzed to produce SiOH groups which subsequently condense to form the SiOSi network. The CsPbBr₃ @FDTS nanocrystals (NCs) are monodispersed cubes with an average particle size of 13.03 nm and exhibit excellent optical stability. Furthermore, the residual hydroxyl groups on the surface of the CsPbBr₃ @FDTS render the NCs tightly packed and cross-linked to each other to form a dense and elastic CsPbBr₃ @FDTS film with soft and hard components. The photodetector based on the flexible CsPbBr₃ @FDTS film exhibits outstanding mechanical flexibility and robust stability after 5000 bending cycles.