Facile Interconversion of [Cp<sub>2</sub>(Cl)Hf(SnH<sub>3</sub>)] and [Cp<sub>2</sub>(Cl)Hf(μ‐H)SnH<sub>2</sub>]: DFT Investigations of Hafnocene Stannyl Complexes as Masked Stannylenes — Julie Guihaumé (2010) | RDL Network
Facile Interconversion of [Cp<sub>2</sub>(Cl)Hf(SnH<sub>3</sub>)] and [Cp<sub>2</sub>(Cl)Hf(μ‐H)SnH<sub>2</sub>]: DFT Investigations of Hafnocene Stannyl Complexes as Masked Stannylenes
Article 2010 en
Authors
JG
Julie Guihaumé
CR
Christophe Raynaud
OE
Odile Eisenstein
Abstract
1 min read
Sn sitzt locker: Der bevorzugte Verlauf für die dehydrierende Kupplung von Stannanen durch den d0-Komplex [Cp2(Cl)HfH] wurde ermittelt (siehe Schema): Auf eine σ-Bindungsmetathese unter Bildung von [Cp2(Cl)Hf(SnH3)] folgt ein Stannyleneinschub in eine Cp2(Cl)Hf-SnH3-Bindung. [Cp2(Cl)Hf(SnH3)] isomerisiert leicht zu [Cp2(Cl)Hf(μ-H)SnH2], einer Spezies mit reaktiver Stannyleneinheit, sodass der Stannylentransfer energetisch möglich wird. Cp=Cyclopentadienyl. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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