The preparation of poly(N-alkyl-3,6-carbazole)s with defined α-/ω-end groups is investigated using a commercial Buchwald-type pre-catalyst. The applied excess of monofunctional aryl halide favored the Suzuki–Miyaura catalyst-transfer polymerization (SCTP) mechanism, leading to heterotelechelic polymers with defined molar masses, narrow dispersities, and high chemical yields (>85%). Notably, the absence of monofunctional aryl halide leads to quantitative formation of conjugated p-type poly(carbazole) macrocycles and the formation of longer chains via step-growth. The SCTP conditions lead to quantitative α-end group identity and up to 50% ω-end group identity due to the incomplete in situ post-polymerization capping step. The end groups were analyzed in depth by MALDI-ToF mass spectrometry on the basis of isotope simulations and relative end group distributions. The fractionation via preparative SEC yielded isolated polymer batches up to 6000 g/mol, very low dispersity values (<1.1), and confirmed end group identities (α: >99%, ω: up to 50%), including reactive azide and/or protected boronic ester end groups.
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