To investigate the toughening effect and stress–strain relationship of steel fibre-reinforced steel slag micropowder ultra-high-performance concrete (UHPC), nine sets of specimens with coarse aggregate and steel fibre contents were prepared for axial compression and elastic modulus tests. This study examines the variations in compressive strength and peak strain of the steel slag micropowder UHPC specimens to determine the corresponding characteristics of the stress–strain relationship. The results indicate that the experimental groups mixed with 1%, 1.5%, and 2% steel fibre increased the peak strain by about 20.3%, 25.3%, and 26.2%, respectively, compared to the non-steel fibre specimens. It can be seen that the toughening effect of UHPC with steel fibre and slag micro powder is good. With a fixed steel fibre content, the compressive strength and peak strain of steel slag micropowder UHPC initially increase and then decrease as the coarse aggregate content increases. The maximum compressive strength is achieved when the steel fibre content is 1.5% and the coarse aggregate content is 20%. A constitutive equation suitable for steel fibre-reinforced steel slag micropowder UHPC was derived through curve fitting based on the experimentally obtained stress–strain curves. The calculated values from the equation show deviations within 10% of the measured values, indicating a good fit. Nonlinear analysis of the entire compression process of prismatic specimens using the finite element method confirms the rationality of the constitutive equation, as the simulated curve closely aligns with the experimental curve. This research findings provide a reference for the engineering application of steel slag micropowder UHPC.
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