Erratum: On the Existence of Our Metals-Based Civilization: I. Phase-Space Analysis [J. Electrochem. Soc., 153, B213 (2006)] — Digby D Macdonald (2007) | RDL Network
7 0.50 Transfer coefficient for Reaction 7 3 Oxidation state of cation in barrier layer 3 or 6 Oxidation state of cation in solution 2.00 106 V/cm Electric field strength k1 00 5.00 10−6 s−1 Base rate constant for Reaction 1 k2 00 1.00 10−11 mol/cm3 s Base rate constant for Reaction 2 k3 00 5.00 10−14 mol/cm3 s Base rate constant for film formation, Reaction 3 k4 00 1.00 10−16 mol/cm3 s Base rate constant for Reaction 4 k5 00 1.00 10−15 s−1 Base rate constant for Reaction 5 k6 00 1.00 10−25 mol/cm3 s Base rate constant for Reaction 6 k7 00 1.00 10−13 mol/cm3 s Base rate constant for film dissolution, Reaction 7 E1–E7 25.1 kJ/mol Activation energy for Reactions 1–7 T0 353.15 K Reference temperature n 0.6 Kinetic order of film dissolution wrt H+
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