Energy‐Efficient Stable Hyperfluorescence Organic Light‐Emitting Diodes with Improved Color Purities and Ultrahigh Power Efficiencies Based on Low‐Polar Sensitizing Systems

Multi-resonance (MR) molecules with thermally activated delayed fluorescence (TADF) are emerging as promising candidates for high-definition displays because of their narrow emission spectra. However, the electroluminescence (EL) efficiencies and spectra of MR-TADF molecules are highly sensitive to hosts and sensitizers when applied to organic light-emitting diodes (OLEDs), and the highly polar environments in devices often lead to significantly broadened EL spectra. In this study, a proof-of-concept TADF sensitizer (BTDMAC-XT) with low polarity, high steric hindrance, and concentration-quenching free feature is constructed, which acts as a good emitter in doped and non-doped OLEDs with high external quantum efficiencies (η_ext s) of 26.7% and 29.3%, respectively. By combining BTDMAC-XT with conventional low-polarity hosts, low-polarity sensitizing systems with a small carrier injection barrier and full exciton utilization are constructed for the MR-TADF molecule BN2. Hyperfluorescence (HF) OLEDs employing the low-polar sensitizing systems successfully improve the color quality of BN2 and afford an excellent η_ext of 34.4%, a record-high power efficiency of 166.3 lm W^-1 and a long operational lifetime (LT₅₀ = 40309 h) at an initial luminance of 100 cd m^-2 . These results provide instructive guidance for the sensitizer design and device optimization for energy-efficient and stable HF-OLEDs with high-quality light.