Enantioselective Reduction of Ketones and Imines Catalyzed by (CN‐Box)Re<sup>V</sup>–Oxo Complexes
Article 2010 en
Authors
KN
Kristine A. Nolin
RA
Richard W. Ahn
YK
Yusuke Kobayashi
Abstract
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Abstract The development and application of chiral, non‐racemic Re V –oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer–Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.
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