Emission estimates of selected volatile organic compounds from tropical savanna burning in northern Australia

Here we present measurements of a range of carbon‐based compounds: carbon dioxide (CO 2 ), carbon monoxide (CO), methane (CH 4 ), nonmethane hydrocarbons (NMHCs), methyl halides, and dimethyl sulfide (DMS) emitted by Australian savanna fires studied as part of the Biomass Burning and Lightning Experiment (BIBLE) phase B aircraft campaign, which took place during the local late dry season (28 August to 13 September 1999). Significant enhancements of short‐lived NMHCs were observed in the boundary layer (BL) over the region of intensive fires and indicate recent emissions for which the mean transport time was estimated to be about 9 hours. Emission ratios relative to CO were determined for 20 NMHCs, 3 methyl halides, DMS, and CH 4 based on the BL enhancements in the source region. Tight correlations with CO were obtained for most of those compounds, indicating the homogeneity of the local savanna source. The emission ratios were in good agreement with some previous measurements of savanna fires for stable compounds but indicated the decay of emission ratios during transport for several reactive compounds. Based on the observed emission ratios, emission factors were derived and compared to previous studies. While emission factors (g species/kg dry mole) of CO 2 varied little according to the vegetation types, those of CO and NMHCs varied significantly. Higher combustion efficiency and a lower emission factor for methane in this study, compared to forest fires, agreed well with results for savanna fires in other tropical regions. The amount of biomass burned was estimated by modeling methods using available satellite data, and showed that 1999 was an above average year for savanna burning. The gross emissions of the trace gases from Australian savanna fires were estimated.