Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center

Patrick W. Smith; Yuyang Dong; T Don Tilley

doi:10.1039/d0sc01749c

Back

Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center

Article 2020 en

Abstract

1 min read

Cationic iron complexes [Cp*(iPr2MeP)FeH2SiHR]+, generated and characterized in solution, are very efficient catalysts for the hydrosilation of terminal alkenes and internal alkynes by primary silanes at low catalyst loading (0.1 mol%) and ambient temperature.

Discussion(0)

No comments yet. Be the first to comment.

Related publications

Article2018

Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing

Patrick W. Smith, T Don Tilley

Article2008

Alkene Hydrosilation by a Cationic Hydrogen-Substituted Iridium Silylene Complex

Elisa Calimano, T Don Tilley

Article2018

Catalytic Olefin Hydrosilations Mediated by Ruthenium η3-H2Si σ Complexes of Primary and Secondary Silanes

Mark C. Lipke, Marie-Noëlle Poradowski, Christophe Raynaud, Odile Eisenstein, T Don Tilley

Article2014

Hypercoordinate Ketone Adducts of Electrophilic η3-H2SiRR′ Ligands on Ruthenium as Key Intermediates for Efficient and Robust Catalytic Hydrosilation

Mark C. Lipke, T Don Tilley

Article2010

N−H Activation of Hydrazines by Iridium(I). Double N−H Activation To Form Iridium Aminonitrene Complexes

Zheng Huang, Jianrong Steve Zhou, John F Hartwig

Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center

Abstract

Discussion(0)

Related publications

Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing

Alkene Hydrosilation by a Cationic Hydrogen-Substituted Iridium Silylene Complex

Catalytic Olefin Hydrosilations Mediated by Ruthenium η<sup>3</sup>-H<sub>2</sub>Si σ Complexes of Primary and Secondary Silanes

Hypercoordinate Ketone Adducts of Electrophilic η<sup>3</sup>-H<sub>2</sub>SiRR′ Ligands on Ruthenium as Key Intermediates for Efficient and Robust Catalytic Hydrosilation

N−H Activation of Hydrazines by Iridium(I). Double N−H Activation To Form Iridium Aminonitrene Complexes