Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

Jian Yang; Verònica Postils; Michael I. Lipschutz; Meg E. Fasulo; Christophe Raynaud; Eric Clot; Odile Eisenstein; T Don Tilley

doi:10.1039/d0sc00997k

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Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

Article 2020 en

Abstract

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A cationic nickel complex of the bis(8-quinolyl)(3,5-di-<italic>tert</italic>-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.

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Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

Abstract

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