Effect of crystalline admixtures on shrinkage and alkali-silica reaction of biochar-cementitious composites

This study investigated effects of crystalline admixture (CA) on shrinkage and alkali-silica reaction behaviours of cementitious composites. Addition of 1-1.5 wt% superabsorbent polymer (SAP) completely mitigated autogenous shrinkage while slightly increasing the 120-day total shrinkage of the SP-cement composite by 5.7%, resulting in the highest apparent porosity. 1-1.5 wt% CA addition did not affect the autogenous shrinkage while slightly reducing the 120-day total shrinkage by 10.1%. The combination of CA and waste wood biochar (WWB) reduced autogenous shrinkage by 24.23% and 120-day total shrinkage by 23.6%, resulting in the lowest apparent porosity. The formation of hydration products in the WWB pores and on WWB surface densified the cementitious matrix, leading to a reduction in water evaporation. Furthermore, for specimens exposed to 1M NaOH solution at 80 °C, CA addition significantly reduced the 120-day expansion by 50.6%, while the combination of CA and WWB addition reduced the 120-day expansion by 42.9%.