Dithiocyanogen Reaction without Cleavage of the SS Bond: Cycloaddition with Hexafluoroacetone

Herbert W. Roesky; Nayla K. Homsy; Mathias Noltemeyer; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1002/anie.198410001

Dithiocyanogen Reaction without Cleavage of the SS Bond: Cycloaddition with Hexafluoroacetone

Angewandte Chemie International Edition 23(12): 1000-1001

Article 1984 English

Abstract

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Dithiocyanogen 1, a typical pseudohalogen, reacts with hexafluoroacetone 2 in a cycloaddition reaction to give the 4H-dioxazine derivative 3. In this reaction—other than in reactions of 1 leading to thiocyanates–the SS bond is not cleaved; the structure of 3 was determined by X-ray diffraction.

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Dithiocyanogen Reaction without Cleavage of the SS Bond: Cycloaddition with Hexafluoroacetone

Abstract

Discussion(0)

Related publications

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