Dalton communications. Synthesis and structure of a stable selenodiimide complex
Journal of the Chemical Society. Dalton transactions: 811-812
Article 1993 English
Authors
JG
J. Gindl
MB
Már Björgvinsson
HR
Herbert W. Roesky
Abstract
1 min read
The stable selenodiimide complex SnCl4[(ButN)2Se]1 has been prepared from Se[NBut(SiMe3)]2 and SnCl4, and also by treating the unstable (ButN)2Se (obtained from NButH2 and SeCl4) with SnCl4; the crystal structure of 1·2thf indicates appreciable SeN double-bond character [171.0(3) pm] but also shows that the selenium atom is unexpectedly co-ordinated by the two tetrahydrofuran (thf) oxygens.
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