[Cp(CO)2Mo{NR*[Rh(norbornadiene)]‐CH(pyridyl)}], a Rhodium Complex with an Asymmetric Molybdenum Atom in the Chelate Skeleton

Henri Brunner; Joachim Wächter; Johann Schmidbauer; In Memory: G.M. Sheldrick (1942–2025); Peter G. Jones

doi:10.1002/anie.198603711

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In Memory: G.M. Sheldrick (1942–2025)

[Cp(CO)2Mo{NR*[Rh(norbornadiene)]‐CH(pyridyl)}], a Rhodium Complex with an Asymmetric Molybdenum Atom in the Chelate Skeleton

Angewandte Chemie International Edition 25(4): 371-373

Article 1986 English

Authors

HB
Henri Brunner
JW
Joachim Wächter
JS
Johann Schmidbauer

Abstract

1 min read

Four centers of chirality—2 × C, 1 × N, 1 × Mo—are present in the title compound 1, R* = (R)-1-CHMePh. Complex 1 is characterized, among other things, by a slightly bent CO group, which is in close contact to Rh. A complicated series of ring openings and epimerizations is suggested as a plausible route to 1.

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[Cp(CO)<sub>2</sub>Mo{NR<sup>*</sup>[Rh(norbornadiene)]‐CH(pyridyl)}], a Rhodium Complex with an Asymmetric Molybdenum Atom in the Chelate Skeleton

Abstract

Discussion(0)

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