A CoP nanoarray behaves as a robust non-noble-metal recyclable catalyst for effective on-demand hydrogen generation from ammonia borane hydrolysis, with an initial turnover frequency and activation energy of 42.8 mol<sub>H2</sub> mol<sub>CoP</sub><sup>−1</sup> min<sup>−1</sup> and 34.1 kJ mol<sup>−1</sup>, respectively.
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