Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-

Laura Turculet; Jay D. Feldman; T Don Tilley

doi:10.1021/om030568r

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T Don Tilley

University of California, Berkeley

Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]-

Article 2003 en

Authors

LT
Laura Turculet
JF
Jay D. Feldman
T Don Tilley
University of California, Berkeley

Abstract

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A series of 14-electron, coordinatively unsaturated Fe(II) silyl complexes featuring the anionic, tripodal phosphine ligand [PhB(CH2PiPr2)3]- have been prepared and characterized; preliminary reactivity studies indicate that at least one such complex can undergo redox processes to generate isolable Fe(I) species with concomitant loss of the silyl ligand.

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Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH<sub>2</sub>P<sup>i</sup>Pr<sub>2</sub>)<sub>3</sub>]<sup>-</sup>

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