Conversion of “LiNS(F)OCMe3” into an (Li8)2 Double Cluster

Wilhelm Isenberg; Rüdiger Mews; In Memory: G.M. Sheldrick (1942–2025)

doi:10.1002/anie.198407951

Conversion of “LiNS(F)OCMe3” into an (Li8)2 Double Cluster

Angewandte Chemie International Edition 23(10): 795-796

Article 1984 English

Abstract

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Nucleophilic substitutions of thiazyl fluoride (NSF) should afford access to thiazyl derivatives RSN. On reaction of NSF with LiOCMe 3 , the primary product “LiNS(F)OCMe 3 ” could be trapped for the first time as the double cluster 1 and subsequently characterized. A molar ratio of NSF: nucleophile of 1:1 is essential for the formation of 1 . equation image

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