Co-extruded triple-layer micro-tubular solid oxide fuel cell: the influence of cathode extrusion rate on the fuel cell properties and performance

Micro-tubular solid oxide fuel cells (MT-SPFC) have emerged as a potential alternative for efficient energy generation. This study investigates the impact of cathode extrusion rates (ranging from 3 to 6 mL min−1) on the triple layer anode/electrolyte/cathode MT-SOFC fabricated via a simplified phase inversion-based co-extrusion/co-sintering technique. Higher cathode extrusion rates (6 mL min−1) indirectly thin the electrolyte layer, improving ion hopping efficiency between the cathode and anode. Moreover, increasing the extrusion rate enhances anode thickness, providing ample electrode reaction sites and thereby enhancing the gas diffusion process. The C6 sample attains a peak power density of 1.46 W cm−2 with 1.08 V OCV at an optimum 800 °C operating temperature, which is high for MT-SOFCs in high-temperature applications. There was a 71.8 % increase in power density for C6 when the temperature changed from 750 °C to 800 °C. The composite cathode material fulfilled both the electronic and ionic conductivity requirements. The optimal cathode extrusion rate for this simplified MT-SOFC fabrication was found to be 6 mL min−1.