ChemInform Abstract: Synthesis of a Highly Reactive (Benzyne)ruthenium Complex: C‐C, C‐H, N‐H, and O‐H Activation Reactions.

John F Hartwig; Richard A. Andersen; Robert G. Bergman

doi:10.1002/chin.198928268

Abstract

1 min read

Abstract The electron‐rich title complex (II) is formed by a process typical of other low‐valent late transition‐metal complexes but its reactions are either unprecedented or similar to those seen with electrophilic d0 benzyne complexes (see scheme).

Related publications

Article1989

Synthesis of a highly reactive (benzyne)ruthenium complex. Carbon-carbon, carbon-hydrogen, nitrogen-hydrogen and oxygen-hydrogen activation reactions

John F Hartwig, Richard A. Andersen, Robert G. Bergman

Article2022

Synthesis, Characterization and Bio-Potential Activities of Co(II) and Ni(II) Complexes with O and N Donor Mixed Ligands

M. Muthuppalani, Ahmed Al Otaibi, S. Balasubramaniyan, S. Manikandan, P. Manimaran, G. Mathubala, A. Manikandan, Muhammad Nadeem Arshad, Madhu Puttegowda, Hajer S. Alorfi, Anish Khan, Abdullah Mohamed Asiri, Mohammed M. Rahman

Article2010

Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex

Lisa D. Julian, John F Hartwig

Article2022

A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant”

Sayanti Chatterjee, Ingolf Harden, Giovanni Bistoni, Rebeca G. Castillo, Sonia Chabbra, Maurice van Gastel, Alexander Schnegg, Eckhard Bill, James A. Birrell, Bill Morandi, Frank Neese, Serena DeBeer

Journal of the American Chemical Society

Article2021

Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes

Eric D. Kalkman, John F Hartwig