ChemInform Abstract: Rhodium‐Catalyzed Enantioselective Silylation of Arene C—H Bonds: Desymmetrization of Diarylmethanols.
Article 2015 en
Authors
TL
Taegyo Lee
TW
Tyler W. Wilson
JB
Jan Bergman
Abstract
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Abstract The hydrosilylation of symmetrical benzophenones (II) and (X) with diethylsilane followed by Rh‐catalyzed asymmetric intramolecular silylation gives rise to chiral benzoxasiloles (IV) and (XI), respectively.
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