ChemInform Abstract: Reactivity of a Sc‐Si Bond Toward CO and CN(2,6‐Me2C6H3). Generation and Reactivity of an Apparent Silene Intermediate Resulting from Isocyanide Coupling at Scandium.

Brian K. Campion; Richard H. Heyn; T Don Tilley

doi:10.1002/chin.199024236

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T Don Tilley

University of California, Berkeley

ChemInform Abstract: Reactivity of a Sc‐Si Bond Toward CO and CN(2,6‐Me2C6H3). Generation and Reactivity of an Apparent Silene Intermediate Resulting from Isocyanide Coupling at Scandium.

Article 1990 en

Authors

BC
Brian K. Campion
RH
Richard H. Heyn
T Don Tilley
University of California, Berkeley

Abstract

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Abstract The reactions of the Sc silyl compound (I) with two equiv. CO (II) in benzene or two equiv. xylyl isocyanide (VII) producing (V) and (VIII) (space group P2 1 /c, Z=4), resp., reveal new chemical processes involving CO‐CO and CN‐Xyl‐CN‐Xyl coupling promoted by a d0 metal center.

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ChemInform Abstract: Reactivity of a Sc‐Si Bond Toward CO and CN(2,6‐Me2C6H3). Generation and Reactivity of an Apparent Silene Intermediate Resulting from Isocyanide Coupling at Scandium.

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