ChemInform Abstract: Iridium‐Catalyzed Borylation of Primary Benzylic C—H Bonds Without a Directing Group: Scope, Mechanism, and Origins of Selectivity. — Matthew A. Larsen (2015) | RDL Network
ChemInform Abstract: Iridium‐Catalyzed Borylation of Primary Benzylic C—H Bonds Without a Directing Group: Scope, Mechanism, and Origins of Selectivity.
Abstract The borylation of methylarenes with a silylborane reagent and a new iridium catalyst containing an electron‐deficient phenanthroline ligand selectively leads to benzylic boronate esters over the corresponding aryl boronate esters.
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