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ChemInform Abstract: Chiral (Acyclic diaminocarbene)gold(I)‐Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters. — Yiming Wang (2011) | RDL Network
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ChemInform Abstract: Chiral (Acyclic diaminocarbene)gold(I)‐Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters.
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Dean Toste
University of California, Berkeley
ChemInform Abstract: Chiral (Acyclic diaminocarbene)gold(I)‐Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters.
Article
2011
en
Authors
+2 more
YW
Yiming Wang
CK
Christian N. Kuzniewski
VR
Vivek Rauniyar
Abstract
1 min read
Abstract The title reaction of phenol‐substituted propargyl pivalates (I) or (III) proceeds via a formal [3,3] sigmatropic rearrangement followed by a 6‐endo‐trig cyclization to give enantioenriched 2‐substituted chromenyl pivalates.
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